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Scrap
tires are a serious disposal problem and continue to
accumulate at increasing rates. If not managed properly,
the scrap tires will present increasing environmental
problems.
By
Nongnard Sunthonpagasit and
H. Lanier Hickman Jr.
Utilization
of scrap tires should minimize environmental impact
and maximize conservation of natural resources. As a
result, both government agencies and environmental groups
have strongly supported scrap tire management programs.
Each state has its own scrap tire laws and regulations
regarding scrap tire storages, collection, processing,
and use. The regulatory practices include landfill bans
and scrap tire fees. Scrap tires can be shredded into
raw materials for use in hundreds of crumb rubber products.
The crumb rubber market has been one of the fastest-growing
scrap tire markets over the last six years. One of the
most interesting and potentially large-volume uses for
crumb rubber is in rubberized asphalt pavement. Although
the rubberized asphalt pavement indicate many advantages,
many state highway departments have not been convinced
of the merits of using rubberized asphalt in a major
capacity. Deterrents for the use of crumb rubberized
asphalt include high initial cost and occasional poor
performance under certain conditions, when compared
to conventional asphalt concrete. However, when one
compares rubberized asphalt to conventional paving on
a life cycle basic, the life cycle costs are less disparate.
INTRODUCTION
The purpose
of this paper is to provide information that will expand
the understanding of the opportunities for the use of
crumb rubber manufactured from scrap tires. The information
presented is current as of the year 2002. This paper
is a summary of a large report prepared and presented
to the Maryland Environmental Service and the Hickman
Intern Program of SWANA. This paper:
- Identifies
current utilization alternatives in the use of scrap
tires.
- Reviews
the current status of markets for scrap tires, uses
of scrap tires as an energy source, civil engineering
applications, and crumb rubber.
- Describes
the current utilization and emerging alternatives
in the use of crumb rubber.
- Identifies
the current and emerging technologies and approaches
to manufacture and market crumb rubber.
- Identifies
the current and emerging crumb rubberized asphalt
technologies.
- Reviews
current status of markets for rubberized asphalt.
- Provides
historical, current, and future crumb rubberized asphalt
activities and obstacles to crumb rubberized asphalt
in specific states. Reponses received from rubberized
asphalt officials and state highway organizations
to a survey aided in the accomplishment of this task.
- Identifies
strong and weak points of using crumb rubber in rubberized
asphalt.
- Recommends
techniques and approaches to overcome the weak points.
SCRAP
TIRES
About 280
million scrap tires (ST) were generated
in the US in 2000 with an annual growth rate of about
26 percent. In addition, about 2 billion scrap tires
have accumulated in stockpiles. A tire is a thermoset
material that contains cross-link molecules of sulfur
and other chemicals. This makes STs very stable and
nearly impossible to degrade under ambient conditions.
STs stored out in the open are potential breeding grounds
for disease-carrying insects and rodents. In addition,
tire fires can be difficult and expensive to extinguish
and can cause environmental problems (Clark et al. 1992,
Jang et al. 1998, Snyder 1998, and USEPA 1993).
SCRAP
TIRE MARKETS AND PRICES
In the U.S.
there are six major markets for scrap tires:
- tire
derived fuel (TDF),
- crumb
rubber (CR),
- civil
engineering applications (CEA),
- export,
- agricultural
uses, and 6) retreading. Figure 1 provides the estimated
total U.S. scrap tire markets from 1994-2000.
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Figure 1
shows that at the end of 2000, the markets for STs were
consuming 66% of the annual generation. The other 34%
of annual generation were either being legally disposed
by placement in landfills or monofills, dumped illegally,
or were going utilized in the retread market (Blumenthal
and Serumgard 1999a). From the end of 1996 through the
end of 2000, the total number of STs going to recovery
or use markets actually decreased. Although the use
of STs as CR and in CEA markets have been increasing,
this increase is not enough to make up for the losses
in the TDF market. However, one difficultly in estimating
the decline in the TDF market from 1996 to 1998 is the
change in calculation methods used to measure capacity
to actual use. There appears to be an actual drop in
usage of TDF from 1998 to 2000. The main reason for
this decrease is an economic boom in construction and
increased productivity requirements for cement kilns
(Serumgard Email-Contact 2001).
SCRAP
TIRE UTILIZATION ALTERNATIVES
Utilization
of STs should minimize environmental impact and maximize
conservation of natural resources. This ideally means
reuse of retread first, followed by reuse of the rubber
to make rubber products or paving, and then combustion
and, ultimately disposal in landfill. Figure 2 summarizes
scrap tire utilization alternatives.
Scrap
Tire Utilization Alternatives
Tire
Derived Fuel (TDF)
STs have
a potential calorific value slightly greater than coal
(> 12,000 Btu). STs can be burned either as a whole
tire or processed into chunk materials (Jang et al.
1998 and Riggle 1994). TDF is considered to be environmentally
safe and the emission products of combustion from burning
tires can be adequately controlled with appropriate
air emission control equipment (UNEP 2000). In fact,
emissions from TDF combustion processes are lower in
moisture content, sulfur content, fixed carbon,
and more chemically homogeneous compared to most types
of coal (STMC Document Undated).
Agricultural
Use
STs are regularly
used in agriculture in a variety of ways; such as used
to weigh down covers at animal feed lots, to protect
fence posts, and used in erosion control and retention
purposes (Blumenthal and Serumgard 1999a and Kearney
1990, 1997, 1999).
Civil
Engineering Applications (CEA)
STs are used
in many CEA, but there are a number of technical, environmental,
and economic constraints that need to be more fully
evaluated (Blumenthal and Serumgard 1999a) than has
occurred to date. While there are hypotheses that shredded
tires can affect water quality, there is no evidences
that the concentration of metals in surface and groundwaters
in contact with STs will fail to meet primary drinking
water standards (DWS). However, the steel
belts exposed at the cut edges of the tire shreds might
increase the levels of iron and manganese (Kearney.
1990. 1997. 1999).
Artificial
Reefs: Artificial reefs are built with STs by bundling
them together, then dropping and anchoring them in coastal
waters. The tires form artificial reefs attractive to
many species of fish in the same way as natural coral
reefs (Clark et al. 1992, Hershey et al. 1987, RCT Vol.
51, Snyder 1998).
Breakwaters:
Tires have excellent energy absorbing characteristics.
As a result they have been used as breakwater barriers
to protect a harbor or shore from wave impacts. Normally
such barriers are built by filling STs with foam rubber
and then lashing them together in modular bundles (Clark
et al. 1992 and OECD 1981).
Backfill
for Wall and Bridge Abutments: STs can be used as
backfill for walls and bridge abutment. The weight of
the tire shreds reduces horizontal pressures on the
wall, allowing for construction of thinner and cheaper
walls. In addition, tire shreds are free draining and
good thermal insulation, which eliminates problems with
water and frost buildup behind the walls (Kearney, 1990,
1997, 1999).
Culverts:
In this application, groups of three whole tires, held
together with steel strapping, are placed side by side
with other groups of three whole times in a trench to
form a culvert. The bottoms of the tires are filled
with sand, which serves as ballast to hold the tires
in place (Epps 1994 and RRI WWW 1999):
Highway
Crash Barriers: STs can be used as highway crash
barriers by binding STs together with steel cable with
a fill of fiberglass or sand. The ST crash barriers
absorb impact of crash from automobiles traveling at
high speeds, reducing the risk of fatality and injury
(Clark et al. 1992 and Jang et al. 1998).
Landfill
Construction and Operation: STs can be used beneficially
in the construction and operation of landfills (Hershey
1999). STs have been used as drainage media in leachate
collection and removal systems. STs have also been used
in surface water run-on/run-off control structures.
In some instances, STs have been used as alternative
daily cover (ADC), but the combustibility and high permeability
properties of tire shreds makes this application questionable.
If used as ACD, it would be prudent to mix tire shreds
with soil prior to placement over the working face.
This should help mitigate the potential for fire hazard
and help reduce rainfall infiltration (CIWMB, 1997,
1998a, 1998b, 1998c, 1998d).
Levee
Reinforcement: In 1998, a reinforcing wall 1,400
feet long and 20 feet deep using 2-inch rubber chips
made from 45,000 STs, was added to the levee of an irrigation
canal in California adjacent to the Feather River. The
levee is being monitored under carefully controlled
water flow and pressure conditions to evaluate the device's
performance on seepage previously occurring at the site
(CIWMB 1999)
Membranes:
The State of Arizona has studied the use of asphalt-rubber
membranes as pond liners and controlling moisture content
in swelling clay soil sub-grades. The study indicates
that asphalt-rubber membranes are cost-effective solutions
for reducing the effects of swelling clay sub-grades
(Epps 1994).
Sludge
Composting: Shredded tires can be used as
a bulking agent in the composting of wastewater treatment
sludges. The main advantage of using tire chips over
wood chips in composting is that the tire chips are
more nearly uniform in size and composition. This uniformity
helps improve air circulation, thereby helping in odor
control. Since tire chips do not degrade, they can be
recovered from the compost mass and used once again
for the composting. A major disadvantage of using tire
chips for sludge composting is the initial cost of the
chips (Clark et al. 1992).
Temporary
Roads: Whole tires can be used to build temporary
roads by binding them together in overlapping patterns
and then laying down directly on soft soils as a road-bed.
They can also be used to build temporary fords at small
stream crossings (Goldberg 1991).
Slope
Stability, Erosion Control, Sub-Grade Fill, and Embankment:
Tire shreds can be used as sub-grade fill, in
the construction of highway embankments and other fill
projects. The purpose of this use is to help stabilize
road beds in crossing swamps and other soft soils where
settlement is a critical factor. STs have also been
used to retain forest roads, protect costal roads from
erosion, enhance the stability of steep slopes along
highways and reinforce shoulder areas (Kearney. 1990.
1997. 1999.). Cost savings over using conventional construction
material can be impressive. For example, use of tire
shreds for lightweight fill in the Portland, Maine highway
embankment saved the Maine Turnpike Authority $300,000
(CIWMB 1999, Clark et al. 1992, and Jang et al. 1998).
Domestic
Reuse and Export
Used tires,
which still have legal tread depths can be resold for
use on other than new motor vehicles. Domestic reuse
appears to be only a negligible percentage of the market
(Clark et al. 1992 and CIWMB WWW 1994). Export of used
tires constitutes a major market for used tires; more
than one million used tires are exported per month (Blumenthal
and Serumgard 1999a).
Disposal
in Municipal Solid Waste Landfills
Disposal
of waste tires in municipal solid waste landfills is
the least desirable method of management. STs or shredded
tires have been banned in many states. Some of these
states include California, Illinois, Iowa, Massachusetts,
and Virginia. However, other states permit the disposal
of shredded or split STs in landfills. Some of these
states are Iowa, Louisiana, and Oklahoma (USEPA 1999
and RCT Vol.51). Advantages for this option are low
capital investment and operating costs, ease of management,
and the possibility for use of the discarded tires in
landfill operations.
Disposal
in Dedicated Monofills
Dedicated
monofills have become more prominent in some locations
as a means to manage STs. Currently shredded STs are
acceptable in monofills in some states, such as Arkansas
and Kansas (USEPA 1999).
Cut,
Stamped, and Punched Products
STs without
steel bead can be stamped or punched to achieve specific
shapes. Examples of products created by this process
are shoe soles, insulators, and fishing equipment (Clark
et al. 1992 and Jang et al.1998). The main obstacles
to the further growth of this industry might be the
inferior quality and aesthetics of such products (Douglah
1995).
Pyrolysis
Pyrolysis
is the chemical breakdown of organic compounds by heating
in the absence of oxygen. Products of pyrolysis are
less complex molecules than the fuel pyrolyzed. Examples
of such products are an oil-like substance (not unlike
bunker C fuel oil), char, carbon black, and in the case
of waste tires, scrap steel (STMC and Jang et al. 1998).
Carbon black is used to produce molded goods, inks,
and pigments. The oil produced by pyrolyzing STs, after
further refining, can be used as a gasoline additive
to increase octane and as fuel (USEPA 1993). The scrap
steel residue from the pyrolyzing of STs is both an
operation and management problem. Pyrolyzing STs, as
a management method, is totally dependent on the cost
of crude oil. This barrier has limited the use of pyrolysis
(Hershey et al.1987).
Reclamation
of Rubber From Waste Tires
Reclamation
of the rubber in waster tires can be done using oil,
water, and reclaiming agents. Reclaimed rubber can be
blended with virgin compounds to produce rubber feedstocks.
The combination of environmental regulations and the
drop in blended rubber markets prices has resulted in
the almost complete elimination of reclaimed rubber
in the US (Baranwal and Klingensmith 1998 and UNEP 2000).
Retreading
Retreading
is a method by which worn tires with usable carcasses,
are given a second life. In the retreading process,
the remaining tread rubber is removed by a grinding
process called buffing, and then replaced with a new
tread. Properly retreaded tires are as structurally
safe and effective as new tires (USEPA 1993). Due to
the high cost of truck tires, the truck tire retreading
business has shown steady growth over the years. Passenger
tire retreading is decreasing because of low prices
of new tires. The retreading tire market is limited
to certain types of tires by the structure and quality
of used tires and user preferences (Clark et al. 1992).
Increased usage of retreaded tires can extend the life
the life of tires, but eventually they will still become
a waste tire requiring management. However, increased
usage of retreaded tires would result in, over time,
fewer waste tires.
CRUMB
RUBBER
This section
discusses the manufacture, uses and markets for crumb
rubber (CR). CR is to describe shreds from scrap/waste
tires that have been reduced to a particle size of 3/8-inch
or less. CR comes from two principal sources - tire
buffings, a retread by-product, and ST rubber (Blumenthal
1997a). In the general ST market, there is no significant
difference between buffings and ST rubber (Blumenthal
and Serumgard 1999a, 1999b). However, it appears that
the ST rubber will be the source of most CR in the future
since retreading is declining. Consequently, the focus
of this section will be on the utilization of ST as
a source for crumb rubber.
Crumb
Rubber Manufacturing Technologies
The finer
the particles size, the higher the surface area, the
cleaner the CR, and the greater the capital investments
for a production plant are general rules in CR production
(Dufton 1995). This section describes current and emerging
crumb rubber manufacturing technologies. The emerging
technologies that are discussed are not currently shelf-item
technology, but offer possibilities for the future
Crumb
Rubber Manufacturing Technologies:
STs can be reduced to crumb rubber by:
- ambient
grinding - a mechanical grinding system that
operates at room temperature and literally tears the
tire material apart, or
- cryogenic
processing - a freezing process where STs
are frozen at very low temperatures by liquid nitrogen,
and then shattered like breaking glass (Blumenthal
and Serumgard 1999b and TNRCC 1999).
Emerging
Crumb Rubber Production Technologies: Two
emerging technologies to reduce STs to crumb rubber
are:
- surface
modification technology - size-reduced rubber
is exposed to either fluoride or bromide gas. The
gas causes a permanent chemical change to the outer
layer molecules of rubber particles, which allows
it to blend with urethane, and
- devulcanization
technologies - devulcanization technologies
break the carbon-sulfur bonds of rubber. These technologies
include ultrasonic, chemical, bio, and ozone-knife
devulcanization technologies. In ultrasonic devulcanization,
STs are exposed to high intensity ultrasonic vibrations.
The resulting energy absorbed by the rubber is theorized
to fracture sulfur-sulfur bonds. Chemical devulcanization
technology blends sulfur and chemical additives with
ST pieces on a mill or in an internal mixer to scissor
sulfur-sulfur bonds by the heat and shear. Bio-processing
technology relates to the biological processes of
microorganisms while ozone-knife technology deals
with ozone-rich atmosphere to break the sulfur-sulfur
bonds. Once these bonds are broken, the material can
be recombined with polymers in a greater percentage
than is currently possible. This recycled rubber can
be used as or is compounded back into virgin rubber
to give lower cost rubber products with good physical
properties (Blumenthal Document Undated, Baranwal
and Klingensmith 1998, CIWMB 2001, Kim and Lee 2000,
Kim and Park 1999, M.F. 1998, RRI WWW 1999, Romine
1998, and ZYN WWW 2001).
Crumb
Rubber Markets
The overall
consumption of CR increased (see Figure 1) about 400
percent during the 1994-2000 period. Although the CR
market offers a greater return on investment than any
other scrap tire market and continues to grow, the prices
for the CR did not trend upward during the period 1994-200.
Therefore, growth in production increased and an industry
expected increase in prices did not. The main reason
for this contradiction is overcapacity. There are many
reasons for this overcapacity including (Blumenthal
and Serumgard 1999a. 1999b, Blumenthal 1997b, Phillips
1996, and Serumgard Email-Contact 2001):
- new
entrants: It takes up to three years for a
newly formed company to develop an end-use market
and become profitable. With such a short time to become
competitive, new entrants have typically put tremendous
downward pressure on CR pricing to secure some market
share.
- failed
enterprises: Since the beginning of 1999,
at least four new CR generators have started operations
and at the same time at least one major producer went
out of business. Failed operations sell their liquidated
remaining inventory at virtually any price just to
move the material.
- imports:
Imports undercut the local market to the detriment
of pricing in the US market.
- paving
markets: Many companies depend on paving applications
with 30 percent of CR being diverted to this segment
annually. It seems that there are not enough paving
applications to go around. Many states highway departments
are not yet convinced to process rubberized asphalt.
Then, companies are looking elsewhere to sell their
product with aggressive in pricing to secure their
market share.
- buffings:
Buffings come from tire retreading processes,
are essentially a by-product, are more easily processed
and are of high quality. As a result, the availability
of tire buffings from retreading operations can depress
the tire CR market.
- glut:
Glut is a sub-standard CR. Some companies just throw
every tire together and grind them up.
Crumb
Rubber Utilization Alternatives
In 2000,
the market place consumed 867 million pounds (23 million
tires) of CR. Of the total 867 million pounds, asphalt
modifications and molded products were almost equal
in market share, and combined had approximately 60%
of the total market, with the remaining 40% going into
the manufacturing of the new products. This section
summarizes the alternative utilization options for crumb
rubber:
- agrimats:The
low thermal conductivity of rubber can provide a warm
bed for animals. This product is resilient, stays
soft, provides a comfortable cushion and energy absorption
characteristics, and does not compact in the way straw
and sawdust does (Dufton 1995). In the case of dairy
cattle, agrimats can increase milk production by 10%
(Snyder 1998).
- automotive
parts: The future of this market depends on
better technical processes, better quality material,
automotive industry influence, and change in image.
Recently, the automotive industry has expressed strong
interest in seeing rubber parts it purchases contain
CR (Blumenthal and Serumgard 1999a). Examples of products
in this market include hoses, friction materials,
and pickup bed liners (RRI WWW 1999).
- filter
medias: Small size CR can be used as a filter
media for biofilters for volatile organic compound
removal and it is cost competitive with other filter
media (Shin 2001).
- footwear
uses: Footwear is an emerging CR molded product
that emphasizes development of both thermoplastic
and thermoset compounds. Nike and Reebok have been
examining the possibilities for producing shoes with
recycled rubber content. With CR incorporation at
only a 20% level, this would represent an annual usage
of 150 million pounds per year (Baldwin et al. 1995).
- molded
and extruded products: In molded
and extruded products, CR is used as a processing
aid and as an extender. An extender improves mold
release, increases the sharpness of moldings, stiffens
the compound, and makes for better control in extrusion
and reduction of die-swell (Dufton 1995). Examples
of the products that can be produced form these methods
include tiles, mats, bumpers, soaker hoses, ramps,
safety surfaces, erosion control, and replacement
for rocks in gravel roads.
- mulch:
Using CR as mulch retains soil moisture, inhibits
weeds, insulates a plant's root structure, and reduces
the amount of pesticides, water and fertilizes needed
in landscaping and agricultural applications. Because
tire material does not readily decompose, mulch made
from tire shreds is not as prone to been replacing
as is mulch from other mulch materials. Although tire
mulch is more expensive initially, it is more economic
over the long term (TNRCC 1999).
- new
tires: CR can be used as a low volume filler
material in the manufacture of several types of tires.
Recently, tire manufactures have been trying to use
approximately 5% CR in the production of new tires.
That might not seem like a lot, but if every tire
made in the U.S. had a 5% CR content, the market for
CR in new tires would increase by more than 185 million
pounds annually (about 6 million STs) (Baldwin et
al. 1995). The State of North Carolina is currently
studying the potential to use 25% CR in the manufacture
of new tires. Safety and new product quality demands
will probably restrain the growth of this market application
(Blumenthal and Serumgard 1999a. 1999b).
- noise
barriers: Molding CR in a state of loose granules
with a polymer-based adhesive enables the production
of noise barriers. Use of CR in noise barriers can
increase the sound absorption capability compared
to other materials used to make noise barriers. As
an example, rubber panels have a better sound absorption
capability than concrete blocks do (RPA WWW 2001,
CIWMB 1997, RRI WWW 2001, and MDE 2000).
- parking
lot surfaces: A porous durable surface made
of fiber-reinforced rubber granules could replace
mulch and sand in non-paved parking lots (ART WWW
2001). There are a number of benefits in using CR
in parking lots including:
- provides
constant traction with superb drainage,
- creates
a resilient surfacing,
- reduces
dust in dry conditions,
- eliminates
puddles and mud problems in wet conditions,
- durable,
- economical
long lasting ground covering, and
- heavier
than water it will not float or blow away.
- railroad
crossings: Recently, rubber has been used
to pave railroad crossing, providing a smooth, safe,
and durable crossing for the vehicle. This technique
also simplifies maintenance problems, such as removal
crossing materials. The installment cost of this rubber
is higher than other materials, such as dirt and gravel,
wood timbers, and concrete, but for the long term
the life cycle cost is lower than competing materials
(Clark 1992 and Snyder 1998).
- rubber
and plastic blends: CR can be used as a component
in mixtures with thermoplastics to extend and modify
the properties of polymeric materials. These blending
materials can be molded or extruded into new products
(Dufton 1995). There appears to be significant market
potential for this application due to continuing research
and development of products (Blumenthal and Serumgard
1999b and Liu et al. 2000).
- rubber
in equestrian areas: Sand in equestrian areas,
such as arenas, is dusty and normally requires an
indoor sprinkler system to control dust. As substitute
product, particulate CR has also found some use here,
because it is soft, safe, and moisture resistant.
This product also reduces injuries to horses and riders,
provides better riding comfort, obtains higher performance,
alleviates the dust problem and provides low maintenance
(Snyder 1998, ART WWW 2001, RTI WWW 2001, McIntire
2000, and TRMA WWW 2001).
- rubber
matting: This market segment is one of the
fastest-growing markets in North America due to the
low price and variety of available colors. 3/8" CR
with all the wire removed can be used as playground
surface cover to improve safety. Rubber mats can replace
asphalt, concrete, stone, sand, wood chips, and packed
earth playground surfaces (TNRCC 1999 and Snyder 1998).
Rubber mats drain well and are cheap, easy to use,
clean, very durable, resilient, nontoxic, and provide
better cushion than other materials. Rubber mats also
do not rot, decay, catch fire, leach, and attract
animals, rodents or insects.
- soil
amendments: CR can be used for soil conditioning
for sport, leisure, and safety surfaces. CR acts as
an aerator and promotes drainage of water, aids water
retention, provides stabilization for the growing
roots of plants and grasses (Dufton 1995), as well
as prevents soil from compacting. CR also improves
the moisture retaining properties of sandy soils and
also the drainage of clay soils. Desert soils have
been rendered more fertile by the use of a CR based
additives.
Currently,
there are two patented soil amendment products on the
market that use CR - Rebound, marketed by American Tire
Recyclers (ATR), and Crown III marketed by Jai Tire
Industries (Rigger 1994 and Snyder 1998). Crown III
is layered on top of the soil and Rebound is mixed into
the soil (Phillips 1996. and 1998 and STMC 1995). All
types of playing fields are candidates for using CR
as soil amendments in the high use areas of the fields.
An example of a high use area, are the areas in front
of the goals where the grass does not grow well. Similarly,
public parks with a high volume of foot traffic are
also candidates for the addition of CR as a soil amendment,
particularly because many of these parks require frequent
resodding. CR has the potential to alter surface characteristics
and increase wear tolerance of turf grass exposed to
traffic (Crum et al.1998, Grunthal 1998, TNRCC 1999,
and Blumenthal and Serumgard 1999a).
- traffic
cones: In the USEPA Comprehensive Procurement
Guidelines, safety cones are required to contain CR
(50-100% by dry weight) when federal funds are used
to purchase the cones. Cones containing CR are of
high quality, widely available, and cost-competitive
with virgin products (USEPA 1997).
- treated
plywood roof sheathings: Treated plywood
roof sheathing is a product of Elastomer Technologies
Inc., used to reduce the slippage characteristics
of plywood sheathing. This product, a latex emulsion
containing CR, is applied to one side of the plywood
at ambient temperature. The latex emulsion serves
as a vapor barrier, waterproofing, and anti-skid surface
(CIWMB 1997).
RUBBERIZED
ASPHALT
Crumb
Rubber Modifier (CRM) for asphalt is a
general term for CR used as a modifier in the asphalt
paving materials. In 2000, CRM consumed around 30 percent
of all the CR sold. Although there is increasing acceptance
of CRM in many states, the demand growth for this market
segment is still uncertain (Dufton 1995 and STMC 1991).
The use of CR in highway applications has a long history
and has been attempted with varying degrees of success
over the years in the USA.
Rubberized
Asphalt Technologies
CR may be
used either as part of the asphalt binder called asphalt
rubber (AR), or as an aggregate substitution called
rubber modified asphalt concrete (RMA). There are two
processes used to incorporate CR, as CRM, into asphalt:
- wet
process - in this process, CR is incorporated
into the asphalt mix with a liquid, such as kerosene
to serve as a blender. The terms "Asphalt Rubber,"
"McDonald" and "Arizona" are interchangeable and used
to describe the wet process.
- dry
process - in this process, a cubical, uniformly
shaped cut CR particle with low surface area in size
from 1/2-1/8 inches is normally used and is blended
dry into the asphalt mix. The terms "Rubber-Modified-Asphalt
(RMA)" and "Rubber-Modified-Hot-Mix-Asphalt (RUMAC)"
are interchangeable and used to describe the dry process.
The Federal
Highway Administration (FHWA) has been promoting CR
in asphalt paving as AR or RMA. Usually one mile of
two-lane road with a three-inch-thick layer uses 1,600
tires for AR and 8,000-12,000 tires for RMA (USEPA 1993).
Factors in determining whether the wet or dry process
are source, type, size, and surface area of CR, asphaltic
and traffic conditions, climate change, technology,
and price (Dufton 1995 and AVP WWW 2001). The smaller
the CR particles, the greater the flexibility there
is for using CR in asphalt paving (Bloomquist et al.
1993).
SuperPave
The Superpave
(SUperior PERforming Asphalt PAVEments)
system is a new emerging technology, developed by the
Strategic Highway Research Program
(SHRP). SHRP is a cooperative effort of the federal
government, state highway agencies, industry, and academia
(Halladay 1998). Superpave is a tool to design asphalt
pavements that will perform better under extremes of
temperature and heavy traffic loads (NCSC WWW 2000).
Superpave
binders are designated with a PG (Performance-Grade)
rating (NECEPT WWW 2001). The binder is evaluated in
the laboratory for the entire range of temperatures
that pavement is expected to be subjected to over its
design life, including extreme high and low temperatures
(KEI WWW 2001). The binder selection is based on the
climate in which the pavement will serve and the traffic
it will bear. The binder types can be selected from
various types of additives, including CRM and other
polymers. Some polymer modified asphalts have a rubber
component and can be graded in a Superpave system. However,
the rubber does not contribute to these mixtures in
any significant degree (Carlson Email-Contact 2001).
Current
Status of Rubberized Asphalt
CRM asphalt
highways in the hot and dry southwestern states of the
US have performed satisfactorily. These states have
extensive experience with AR. Figure 3 shows photos
of a four-inch-asphalt-concrete-overlay (Left) and a
two-inch-AR-pavement over a two-inch-asphalt-concrete-leveling-course
(Right). Both sections were placed over cracked and
sealed concrete. Test sections were constructed in 1990
on I-40 near Flagstaff, Arizona. The photos indicate
that the AR-pavement is outperforming the ConVentional
Asphalt (CVA). The AR section depicts reduced
cracking (Carlson and Zhu 1999 and RPA News 1998).
CRM asphalt
highways in the wet and cold northern states of the
US have performed poorly or equal when compared to the
CVA. The main reason for these failures appears to be
weather-affected construction problems, where ambient
temperature is required for construction. However, the
exact cause of various pavement failures is not known.
Figure 4 shows photos of a CVA (left) and an AR-concrete
containing 14 percent fine CR (right). Test sections
were placed in 1993 on Route I-44, Phelps County, Missouri
and an evaluation was conducted in 1998. Both photos
show low severity longitudinal cracking in the center
section of the driving lane. However, overall the AR
test section performed as well as the CVA (Trautman
and Williams 1999).
Figure
3
Performance
of CVA (Left) and AR Pavement (Right) in Arizona
Source: RPA
News 1998
Figure
4
Performance
of CVA (Left) and AR Pavement (Right) in Missouri
Source: Trautman
and Williams 1999
The following
data and information was gathered primarily through
personal e-mail contact by the senior author with State
Highway Agencies and organizations relating to the CRM
asphalt.
- A number
of states including Illinois, Maryland, Oklahoma,
and Ohio have experienced problems using CRM asphalt.
The problems include cost ineffectiveness, poor performance
or equal performance compared to CVA, and poor mix
qualities, when compared to CVA.
- North
Carolina, Illinois, Indiana, Kentucky, Missouri, Montana,
Nevada, Ohio, and Oklahoma have no plans to use CRM
asphalt in the near future.
- Iowa,
Maryland, Michigan, New York, Rhode Island, Virginia,
and Washington allow the use of CRM asphalt if the
mixture properties meet the requirements in Superpave.
However, due to the higher costs to produce this binder,
the use of CR in this technique is not being used
extensively.
- A number
of states including California, Connecticut, New York,
and Texas have had good experiences using CRM asphalt.
Results show excellent construction ability and performance,
maintenance-free performance, and increasing life
cycle. Both wet and dry processes have been used extensively
in California. Texas is increasing its annual CRM
asphalt usage due to CR availability at a competitive
price. New York allows the use of CRM asphalt produced
by the wet process at the contractor's option.
Comparing
CRM Asphalt and Conventional Asphalt
CRM asphalt
is comparable to CVA as a paving material. The initial
cost of CRM asphalt is higher that CVA. However, when
the two pavements are compared on a life cycle
basic (LC), the LC costs for CRM asphalt are less costly.
The lower LC costs can be attributed with the longer
life span of CRM asphalt. LC cost factors that make
this possible include reduced cost of construction,
inspection, and maintenance, fewer traffic inconveniences,
less construction noise, and other inconveniences to
the public (RACTC WWW 2001). Noise studies in Western
Europe and the US show that the use of AR can reduce
traffic noise as much as 85%. The advantages and disadvantages
of using CRM are summarized in Table 1.
Principal
Barriers Limiting the Use of CRM Asphalt Pavement
Although
the test results indicate many advantages, many state
highway departments have been unwilling to use asphalt
rubber paving. The primary states using CRM asphalt
is still limited to California, Arizona, Texas, and
Florida. Legislative, economic, technical, sociological,
and environmental barriers limit the use of CRM asphalt
elsewhere in the US.
Legislative/Regulatory
and Political Barriers: The US Congress
passed Intermodal Surface Transportation
Efficiency Act (ISTEA) in 1991, addressing the
use of scrap tires in transportation facilities. Subsection
1038(d) of the act, "Use of Recycled Paving Materials,"
requires states to use scrap tire in federal funded
highways. The requirement began in 1994 at the level
of 5% to a maximum of 20% in 1997 and each year thereafter.
If this act were implemented, it would have increased
the use of scrap tires from 17 million in 1994 to 70
million in 1997 (USEPA 1993). However, in 1995 ISTEA
was repealed, presumably as a matter of politics and
lobbying efforts of the asphalt industry. As a result,
the use of CRM asphalt now depends on the willingness
of the state's DOT to begin their programs (Blumenthal
and Serumgard 1999).
| Table
1: Advantages and Disadvantages of CRM Asphalt |
|
Items
|
Advantages
|
|
Costa
|
reduced
LC, maintenance, contracting, inspection, sound
barrier costs.
|
|
Constructiona
|
reduces
construction noise and public and traffic inconveniences.
|
|
Mixture
|
increases
the temperature viscosity and provides more ductility
to the mix at low temperatures.
|
|
Road
Performance
|
provides
cracking resistance and long-lasting color marking,
increases surface toughness and flexibility characteristics.
|
|
Vehicles
|
provides
greater skid resistance, better road holding,
and less spalling of the surface, reducing vehicles
damage.
|
|
Scrap
Tires
|
preserves
landfill space and provides a tire disposal solution.
|
|
Noise
|
reduces
traffic noise.
|
|
Drainage
|
improves
drainage and reduced motorway spray.
|
|
Items
|
Disadvantages
|
|
Construction
|
for
wet process, CRM asphalt must to be used within
hours of production, then the mobile units required.
|
|
Cost
|
-
increased initial costs per mile. These costs
include increase asphalt content, energy consumption,
and CRM material.
- increased
the investment costs due to modification requirements
that have to be made to the plant, paving, design,
and mixing equipment.
-
for wet process, increased the cost of mobile
equipment and setup.
|
|
Environment
|
concerns
about air emission, worker safety, and recycle
ability.
|
|
Mixture
|
- increases
mixing temperature.
-
requires unique aggregate gradation, asphalt
and filler content design, and a greater overall
filler and asphalt cement volume.
- for
wet process, deteriorate at elevated temperatures.
|
Economic
Barriers: The economic barriers
include high initial cost, high capital investment,
LC analysis, funding sources, and patents:
- high
initial cost - There is an increased cost
associated with using CRM asphalt over CVA. The factors
affecting this include increased asphalt content,
energy consumption, and cost of CRM (Dufton 1995).
The price for a ton of A-R hot mix is typically $10
more per ton than CVA (Carlson Email Contact 2001).
In general, the cost per mile of laid pavement or
road maintenance increases by 50-100% over CVA, even
though the road surface life is extended by 150-300%
(Secretariat's Statistician 2000). Therefore, even
though initial cost is higher, CRM asphalt roads cost
less when considered on a LC basis.
- high
initial capital investment costs - The main
reason for high initial capital investment costs are
associated with necessary modifications to mixing/batching
plants, paving design, and compacting equipment to
ensure proper crumb rubber mixing. The capital investment
for A-R binding equipment is not unreasonable for
a paving contractor. However, it is unreasonable if
specifications allow CRM contractors to have to bid
against non-CRM contractors (Carlson Email-Contact
2001).
- life
cycle cost analysis - There is no standard
LC cost analysis available to evaluate the LC costs
of CRM compared to CVA. Many study results are unclear,
are not relevant to all applications, lack long-term
performance data, and have different input variables,
making comparisons difficult.
- funding
sources -State subsidies or grants to encourage
the use of CRM asphalt are limited. Due to the high
initial cost, it is difficult for state or local governments
to increase the highway investment or make increased
lifecycle cost to be their main goal. Instead, many
set goals of a certain number of road miles to be
paved per year. Since cost is often the critical factor,
the long-term advantages of CRM asphalt are usually
suppressed in favor of short-term savings (Secretariat's
Statiscian 2000).
- patents
- Some techniques are patented, which add costs to
the process. It is estimated that cost increases by
35% and 27% by using McDonald and PlusRide process,
respectively. As a result of expiration of the McDonald
patent in 1992, since then, more CRM application contractors
are becoming involved (Baldwin 1995 and Gauff Email
Contact 2001). However, this decrease in costs is
still not competitive when compared with CVA costs.
Technical
Barriers: The American Society for
Testing and Materials (ASTM, the national voluntary
setting standard organization) has not established standards
for CRM asphalt. In addition, there is a lack of data,
presented in a comparative and standard form, of long-term
tests to demonstrate the efficacy of CRM asphalt as
a paving material. As a result, other materials with
ASTM standards and long-term performance/test data histories
have a competitive and technical advantage over CRM
asphalt (Kearney 1990, 1997, 1999).
Sociological
Barriers: Many states have conducted
research on CRM asphalt during the ISTEA mandate era.
Many tests were unsuccessful. As a result, many state
DOTs are reluctant to try CRM regardless of the benefits
it might provide (Carlson and Zhu 1999). Moreover, contractors
or engineers are often reluctant to change from materials
that are proven and in common use.
Health
and Environmental Barriers: Health
and environmental studies of the effects of CRM have
been conducted by many organizations. This section summarizes
the conclusions from those studies.
- air
emissions - Emission tests were conducted
in California and Canada (CIWMB 1997 and Sainton and
Takallou 1992). Testing results reported through 1993,
have shown no obvious trend of significantly increased
or decreased emissions that can be attributed to the
use of CRM pavement production (FHWA and USEPA 1993).
Tests have also indicate that there is no evidence
that workers involved in the production and construction
of CRM pavement are exposed to increased risk when
compared to workers involved in the production and
construction of CVA pavement.
- recycling
- California conducted a study of the recyclability
of CRM pavement in 1994. The results indicate that
the CRM asphalt can be recycled using either microwave
technology or conventional mix design. Additionally,
the report indicates that during paving recycling,
the employee exposures to air contaminants were below
the Occupational Safety and Health Administration
(OSHA) permissible exposure limits (PEL) (Carlson
and Zhu 1999). Moreover, in six projects in the US,
CRM pavement material has been recycled as a portion
of the aggregate in a new asphalt paving (RMRC WWW
2001). The results from the use of the aggregate have
not been reported in the literature at the time this
paper was prepared.
Overcoming
Barriers: There are many barriers
that deter the use of CRM asphalt. The future of CRM
asphalt will depend on how successfully those barriers
are overcome. Proponents of CRM asphalt have proposed
a number of initiatives to help reduce, or at least
minimize the impact of these barriers:
- provide
potential funding mechanisms to help address the initial
cost difference between CRMA and CVA including (Douglah
1995):
- tire
disposal fees assessed on new tire purchases,
- tipping
fees collected at the point of tire disposal, or
- vehicle
title registration/transfer fees.
- support,
promote, and fund studies regarding CR and CRM. The
following studies are needed to develop criteria for
increasing the use of CRM:
- LC
cost analysis to determine cost effectiveness,
- quality
control programs to allow continuous monitoring
of the uniformity of the product for chemical composition
and gradation (Heitzman 1992),
- environmental
studies related to production, use and recycling
of RMA asphalt,
- ASTM
standards to provide technical information on product
quality, process information, and production specifications,
- CRM
pavement technology development to determine the
optimum mix for the spectrum of anticipated environmental
and road conditions that CRM asphalt would be used
and the optimum method with the lowest cost of CRM
asphalt (Broughton 1994), and
- mixture
design method to accommodate the use of CRM. The
combined influence of CRM particle size, amount,
and aggregate gradation needs to be evaluated for
each application (Bloomquist et al. 1993).
- educate
engineers, the academic community, the federal government,
state agencies, and public and private contractors
about the advantages and disadvantages of CRM asphalt.
Various options are available for such education:
- public
educational workshops, seminars, and conferences
on CRM asphalt,
- provide
training and consultation services, or
- publish
a comprehensive CRM asphalt technology guideline
report.
- stimulate
corporation among the industries, EPA, FHWA, States,
and other government agencies to share information
and to study the feasibility of using CRM asphalt,
- convince
the FHWA to provide state DOTs with more details and
guidance regarding the use of CRM pavement in their
states,
- find
a way to address the price differences between CRM
asphalt and CVA,
- develop
more markets for CRM asphalt use,
- provide
research grant support for CRM asphalt R&D,
- assist
manufacturers to develop equipment and methods to
produce CRM asphalt at cost effective prices, and
- enact
legislation, guidelines, and regulations at the federal
and state levels, and ordinances at local government
levels to encourage CRM asphalt usage where practical.
SUMMARY
Uses
for Scrap Tires
Approximately
280 million ST were generated in the US in 2000. Approximately
66% of these tires were consumed in tire derived fuel
(TDF), civil engineering applications (CEAs), crumb
rubber (CR), exports, agricultural and other miscellaneous
uses. The three applications that have the most potential
for increased use are TDF, CEA, and CR.
Scrap
Tires as an Energy Source (TDF)
From
the end of 1996 through the end of 2000, the total market
for scrap tires to be used as TDF market decreased.
However, the economic advantage of using scrap tires
as TDF might increase in the future.
Civil
Engineering Applications (CEA)
The CEA market
increased over about 250% during the 1994-2000 period.
STs can be used in many CEA. Because of the economic
advantage that STs offer over competing materials, the
CEA market is expected to increase in the future.
Crumb
Rubber (CR)
The CR market
has been one of the fastest-growing since 1995. While
the use of CR increased, the price of CR did not trend
upward as the industry expected. The main reason for
this contradiction is the overcapacity. The CR market
is expected to expand in the future, but continue to
have the same high degree of risk. The pattern for CR
manufacturing is normally that companies enter the business
and are forced out of business over a relatively short
time period due to the low market prices.
In 2000,
asphalt modifications and molded products had approximately
60% of the total CR market, with the remaining 40% going
into the manufacturing of the new products.
Market availability
is a function of cost and product quality or characteristics.
Currently, applications for CR are becoming more complex
and the product needed necessitates production of smaller
particle size material. The lack of national standards
for CR product hinders the growth in what has become
a quality driven market.
The common
processes for manufacturing CR are ambient and cryogenic
grinding. In the general scrap tire market, there is
no significant difference in the product produced by
either process. However, these processes differ in both
techniques and product characteristics. The general
rule in the manufacture of CR is that the finer the
particle size, and the cleaner the crumb rubber, then
the greater the required capital investment for a plant.
Surface modification and devulcanization technologies
are emerging CR technologies that offer possibilities
for the future.
Rubberized
Asphalt Pavement
One of the
most interesting and potentially large-volume uses for
CR is in rubberized asphalt pavement. Since the 1960s,
many states have conducted research on crumb rubber
modifier (CRM) as an additive to asphalt since1960's.
Research has studied both wet and dry processes with
neither process emerging as the process of choice. Test
results show many advantages to use CRM asphalt including:
- improving
fatigue and skid resistance,
- improving
durability,
- reducing
temperature susceptibility,
- reducing
traffic noise,
- reducing
temperature stiffness and cracking, and
- increasing
the life cycle (LC) of asphalt pavement.
However,
doubts still remain about life expectancy, recyclability,
emission safety related to the production and construction
of asphalt pavement, and application techniques for
different climates. These doubts are important and must
be addressed when considering CRM asphalt pavement.
Furthermore, the greatest deterrents for the use of
CRM are high initial cost and occasional poor performance
under certain conditions, when compared to conventional
asphalt (CVA). As a result, many state highway departments
are not yet prepared to include CRM asphalt as an accepted
alternative in highway paving.
Additionally,
a survey of the states indicates that many states are
using the Superpave method to design asphalt pavements.
CR may be used in this method as a rubber modified mixture,
depending on the paving contractor and price. However,
the deterrent for the use of CRM in this method is high
production cost. As a result, there has not been extensive
use of CR using the Superpave design method even though
it is an accepted alternative in highway paving.
Overcoming
Barriers Limited the Use of Crumb Rubberized Asphalt
The future
of rubberized asphalt will depend on how successfully
the technical, economic, and attitudinal barriers are
overcome. Several actions can be taken by state and
local governments to help reduce, or at least minimize
the barriers that impede the use of CRM asphalt. These
actions include:
- create
funding sources to encourage use of CRM asphalt,
- finding
financial means to support various CRM R&D activities,
- educating
designers and paving project buyers in the use of
CRM asphalt, and
- finding
means to overcome the price difference between CRM
asphalt and CVA roads.
CONCLUSIONS
Crumb rubber
is a new emerging material, which has been suggested
as a solution for a large portion of scrap tires. Crumb
rubber markets might be sufficiently large enough to
ensure long-term scrap tire management capacity. However,
crumb rubber markets are in the adolescent evolutionary
stage and further research is needed to expand this
market. Rubberized asphalt is comparable to conventional
asphalt paving. It is more costly to use when initial
costs are compared but when one compares on a life cycle
basic, the life cycle costs are less costly. The cost
per cubic yard CRM asphalt can be lower by as much as
13 to 33 percent over its life in an asphalt paved road.
The future of rubberized asphalt will depend on the
willingness of state highway departments to include
rubberized asphalt in their road paving programs. If
these products can demonstrate cost effective performance,
production and application techniques, and environmentally
acceptability, then CRM could become a major method
for the management of great quantities of rubber from
scrap tires.
REFERENCES
AND BIBLIOGRAPHY
AERPI
(Alberta Environmental Rubber Products) World Wide Web.
2001. Link: AERP Photo Gallery Home Page: www.aerpi.com/index1.htm.
Allen,
G. 1993. A review of Different Methods of Recycling
Tyres. Presented at Rubber Europe '93 Conference, The
Congress Centre, Hague, Netherlands. 214-221.
Amirkhanian,
S.N. 2000. Waste Tires Cut Costs of Building New Highways.
BioCycle. 46-47, December.
Amirkhanian,
S.N. and Burati, J.L. 1996. Utilization of Waste
Tires in Asphaltic Materials, FHWA-SC-96-02. South
Carolina Department of Transportation. Columbia, SC.
June.
ART
(American Rubber Technologies, Inc. World Wide Web).
2001. Link: State of the ART Rubber Recycling
Facility Home Page: www.americantire.com.
AVP
(American Virtual Production Co.) World Wide Web. 2001.
Link: Crumb Rubber Modifier Technology Home Page: http://www.bei-emulsions.com/rubber.htm.
Baldwin,
S.D., Cornell, D.D., Rader, C.P., Sadler, G.D., and
Stockel, R.F. 1995. Plasti |